(η3-allyl)[(S)-(+)-(2-pyrrolidinylmethyl)pyrrolidine]palladium(II) trifluoromethanesulfonate

被引：5

作者：

Jones, MD ^{[1
]}

Paz, FAA ^{[1
]}

Davies, JE ^{[1
]}

Johnson, BFG ^{[1
]}

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803003507

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Pd(C3H5)(C9H18N2)]CF3SO3, crystallizes in the non-centrosymmetric space group P2(1)2(1)2(1) and contains only one crystallographically unique Pd metal centre, showing a pseudo-square-planar geometry. (S)-(+)-(2-Pyrrolidinylmethyl)pyrrolidine (pmp, C9H18N2) acts as an N,N'-bidentate chelating ligand, leading to the formation of the chiral [Pd(eta(3)-allyl)(pmp)](+) complex cation, which is hydrogen bonded to the trifluoromethanesulfonate anion.

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页码：M105 / M107

页数：3

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