Conducting polypyrrole with nanoscale hierarchical structure

被引：42

作者：

Han, Yongqin ^{[1
,2
]}

Qing, Xutang ^{[1
]}

Ye, Sunjie ^{[1
]}

Lu, Yun ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, State Key Lab Coordinat Chem, Dept Polymer Sci & Engn, Nanjing 210093, Peoples R China

[2] Nanjing Univ Aeronaut & Astronaut, Coll Mat Sci & Engn, Nanjing 210016, Peoples R China

来源：

SYNTHETIC METALS | 2010年 / 160卷 / 11-12期

基金：

中国国家自然科学基金;

关键词：

Polypyrrole; Nanoscale hierarchical structure; Supramolecular templates; ELECTROCHEMICAL SYNTHESIS; POTENTIAL APPLICATIONS; CHEMICAL-SYNTHESIS; NANOWIRE NETWORKS; CONTROLLED GROWTH; AQUEOUS-SOLUTION; POLYANILINE; TEMPLATE; NANOFIBERS; NANOSTRUCTURES;

D O I：

10.1016/j.synthmet.2010.03.002

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Conducting polypyrrole (PPy) with nanoscale hierarchical structure is chemically synthesized in an aqueous solution in the presence of cetyltrimethylammonium bromide (TAB) and 1,5-naphthalene disulfonic acid (1,5-NDA). The effect of synthetic conditions including concentration of CTAB and pyrrole. reaction temperature, oxidants and their introduced modes on the PPy hierarchical nanostructure is systematically investigated. A hypothesis for the hierarchical structure formation of PPy with the aid of CTAB/1,5-NDA/pyrrole supramolecular template is presented, in which the pyrrole is polymerized in imitation of the CTAB/1,5-NDA/pyrrole crystal shape. The electrochemical performances of representative PPy sample show that the PPy with hierarchical nanostructures has potential application as supercapacitor materials. (C) 2010 Elsevier B.V. All rights reserved.

引用

页码：1159 / 1166

页数：8

共 40 条

[1]

Agarwal B.K., 1991, XRAY SPECTROSCOPY IN

[2]

AOYAMA Y, 1998, SCIENCE, V280, P557

[3] Controlled syntheses of conducting polymer micro- and nano-structures for potential applications [J].