Electrophoretic deposition of ceramic materials for fuel cell applications

被引:141
作者
Zhitomirsky, I [1 ]
Petric, A [1 ]
机构
[1] McMaster Univ, Dept Mat Sci & Engn, Hamilton, ON L8S 4L7, Canada
关键词
ZrO(2); (Ce; Gd)O(2); electron microscopy; electrophoretic deposition; fuel cells; (La; Sr)(Co; Fe)O(3); Sr)(Ga; Mg)O(3); suspensions; tape casting;
D O I
10.1016/S0955-2219(00)00098-4
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 [材料科学与工程]; 080502 [材料学];
摘要
La(0.8)Sr(0.2)Ga(0.875)Mg(0.125)O(3-x) (LSGM), La(0.8)Sr(0.2)Co(0.2)Fe(0.8)O(3-delta) (LSCF), yttria stabilized zirconia (YSZ) and (Ce(0.8)Gd(0.2))O(1.9) (CGO) were electrophoretically deposited on Ni foils and Ni-yttria stabilized zirconia substrates prepared by tape casting. It was demonstrated that the ethyl alcohol-phosphate ester-polyvinyl butyral system is an effective solvent-dispersant-binder system for electrophoretic deposition of these materials. The influence of dispersant, binder and current density on deposition efficiency and deposit morphology was studied. The microstructure of the deposits was examined by electron microscopy. The proposed solvent-dispersant-binder medium for electrophoretic deposition of LSGM, LSCF, YSZ and CGO has important advantages and implications in fuel cell design. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2055 / 2061
页数:7
相关论文
共 42 条
[1]
Bouyer F, 1999, J AM CERAM SOC, V82, P2001, DOI 10.1111/j.1151-2916.1999.tb02032.x
[2]
CHARTIER T, 1987, AM CERAM SOC BULL, V66, P1653
[3]
ELECTROPHORETIC DEPOSITION OF CALCIUM PHOSPHATES FROM NONAQUEOUS MEDIA [J].
DAMODARAN, R ;
MOUDGIL, BM .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1993, 80 (2-3) :191-195
[4]
Ceramic materials containing rare earth oxides for solid oxide fuel cell [J].
Eguchi, K .
JOURNAL OF ALLOYS AND COMPOUNDS, 1997, 250 (1-2) :486-491
[5]
El-Sherik A. M., 1998, Proceedings of the Third International Symposium on Ionic and Mixed Conducting Ceramics, P643
[6]
FOISSY AA, 1982, CERAM B, V61, P251
[7]
Gani M.S.J., 1994, IND CERAM, V14, P163
[8]
ELECTROPHORETIC DEPOSITION OF LUMINESCENT MATERIALS [J].
GROSSO, PF ;
RUTHERFO.RE ;
SARGENT, DE .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1970, 117 (11) :1456-&
[9]
Superior oxygen ion conductivity of lanthanum gallate doped with strontium and magnesium [J].
Huang, PN ;
Petric, A .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1996, 143 (05) :1644-1648
[10]
PREPARATION OF YTTRIA-STABILIZED ZIRCONIA FILMS FOR SOLID OXIDE FUEL-CELLS BY ELECTROPHORETIC DEPOSITION METHOD [J].
ISHIHARA, T ;
SATO, K ;
MIZUHARA, Y ;
TAKITA, Y .
CHEMISTRY LETTERS, 1992, (06) :943-946