Influence of the guest molecule on the rotational motions of ammonia groups in Hofmann clathrates

被引:6
作者
Vorderwisch, P [1 ]
Hautecler, S [1 ]
Kearley, GJ [1 ]
Kubanek, F [1 ]
机构
[1] INST MAX VON LAUE PAUL LANGEVIN,F-38042 GRENOBLE,FRANCE
来源
PHYSICA B | 1997年 / 234卷
关键词
intercalation; rotational modes; tunnelling; QUANTUM;
D O I
10.1016/S0921-4526(96)00882-4
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
INS experiments on Hofmann clathrates Ni-Ni-G with various guest molecules G give rotational level schemes for NH3, in Ni-Ni-C6H6 and Ni-Ni-C12H10 identical with those in Ni-Ni-C6D6. For polar guest molecules, tunnelling transitions indicative for moderately strong hindering potentials are observed.
引用
收藏
页码:68 / 69
页数:2
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