Recognition of 1,2-diazines by a bidentate Lewis acid

被引：43

作者：

Gabbaï, FP

Schier, A

Riede, J

Hynes, MJ

机构：

[1] Tech Univ Munchen, Inst Anorgan Chem, D-85747 Garching, Germany

[2] Natl Univ Ireland Univ Coll Galway, Dept Chem, Galway, Ireland

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 08期

关键词：

D O I：

10.1039/a800413g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dimeric ortho-phenyleneindium bromide 1 shows a higher affinity for 1,2-diazines than for 1,3- and 1,4-diazines; as shown by the X-ray crystal structure analysis of the host-guest complex 3 the observed selectivity results from subtle structural variation which can bring the indium p orbitals to converge.

引用

页码：897 / 898

页数：2

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