Stereoselective epoxidation of electron poor dienes using poly(L-leucine)

被引：20

作者：

Allen, JV

Cappi, MW

Kary, PD

Roberts, SM

Williamson, NM

Wu, LE

机构：

[1] Department of Chemistry, University of Liverpool, Liverpool

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 22期

关键词：

D O I：

10.1039/a706238i

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Poly(L-leucine) catalysed oxidation of dienes 2, 3, 10, 16 and 18 and the triene 17 furnishes the corresponding epoxides 4, 5, 11, 19, 21 and 20 respectively in good to excellent yield and in states of high optical purity, Some regioselective reactions of the saturated epoxy ketones 5 and 11 are described.

引用

页码：3297 / 3298

页数：2

共 7 条

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