Stereoselective epoxidation of electron poor dienes using poly(L-leucine)

被引:20
作者
Allen, JV
Cappi, MW
Kary, PD
Roberts, SM
Williamson, NM
Wu, LE
机构
[1] Department of Chemistry, University of Liverpool, Liverpool
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1997年 / 22期
关键词
D O I
10.1039/a706238i
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Poly(L-leucine) catalysed oxidation of dienes 2, 3, 10, 16 and 18 and the triene 17 furnishes the corresponding epoxides 4, 5, 11, 19, 21 and 20 respectively in good to excellent yield and in states of high optical purity, Some regioselective reactions of the saturated epoxy ketones 5 and 11 are described.
引用
收藏
页码:3297 / 3298
页数:2
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