Gas and liquid chromatography with inductively coupled plasma mass spectrometry detection for environmental speciation analysis - advances and limitations

被引：50

作者：

Szpunar, J ^{[1
]}

McSheehy, S ^{[1
]}

Polec, K ^{[1
]}

Vacchina, V ^{[1
]}

Mounicou, S ^{[1
]}

Rodriguez, I ^{[1
]}

Lobinski, R ^{[1
]}

机构：

[1] CNRS, EP 132, F-64000 Pau, France

来源：

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY | 2000年 / 55卷 / 07期

关键词：

speciation; chromatography; inductively coupled plasma mass spectrometry; biological; environmental;

D O I：

10.1016/S0584-8547(00)00210-X

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Recent advances in the coupling of gas chromatography (GC) and high performance liquid chromatography (HPLC) with inductively coupled plasma mass spectrometry (ICP MS) and their role in trace element speciation analysis of environmental materials are presented. The discussion is illustrated with three research examples concerning the following topics: (i) development and coupling of multicapillary microcolumn GC with ICP MS for speciation of organotin in sediment and biological tissue samples; (ii) speciation of arsenic in marine algae by size-exclusion-anion-exchange HPLC-ICP MS; and (iii) speciation of cadmium in plant cell cultures by size-exclusion HPLC-ICP MS. Particular attention is paid to the problem of signal identification in ICP MS chromatograms; the potential of electrospray MS/MS for this purpose is highlighted. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：779 / 793

页数：15

共 32 条

[1] Analytical procedures for the determination of organotin compounds in sediment and biota: a critical review [J].