Novel sulfonated carbonaceous materials from p-toluenesulfonic acid/glucose as a high-performance solid-acid catalyst

被引:151
作者
Zhang, Baohua [1 ]
Ren, Jiawen [1 ]
Liu, Xiaohui [1 ]
Guo, Yun [1 ]
Guo, Yanglong [1 ]
Lu, Guanzhong [1 ]
Wang, Yanqin [1 ]
机构
[1] E China Univ Sci & Technol, Adv Mat Lab, Res Inst Ind Catalysis, Shanghai 200237, Peoples R China
基金
中国国家自然科学基金;
关键词
Carbon based; Solid-acid catalyst; Thermal treatment; Succinic acid esterification; MESOPOROUS SILICA; BISPHENOL-A; ESTERIFICATION; BIODIESEL;
D O I
10.1016/j.catcom.2010.01.010
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A novel carbon-based solid-acid catalyst was simply prepared for the first time by the thermal treatment of p-toluenesulfonic acid (TsOH) with D-glucose at 180 degrees C in a sealed autoclave and it was proved to have high acidity and to be a highly efficient solid-acid catalyst in the reactions such as esterification of succinic acid with ethanol. Crown Copyright (C) 2010 Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:629 / 632
页数:4
相关论文
共 25 条
[1]   Towards a bio-based industry: Benign catalytic esterifications of succinic acid in the presence of water [J].
Budarin, Vitaly ;
Luque, Rafael ;
Macquarrie, Duncan J. ;
Clark, James H. .
CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (24) :6914-6919
[2]   Starbons: New starch-derived mesoporous carbonaceous materials with tunable properties [J].
Budarin, Vitaly ;
Clark, James H. ;
Hardy, Jeffrey J. E. ;
Luque, Rafael ;
Milkowski, Krzysztof ;
Tavener, Stewart J. ;
Wilson, Ashley J. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (23) :3782-3786
[3]   Versatile mesoporous carbonaceous materials for acid catalysis [J].
Budarin, Vitaly L. ;
Clark, James H. ;
Luque, Rafael ;
Macquarrie, Duncan J. .
CHEMICAL COMMUNICATIONS, 2007, (06) :634-636
[4]   Catalytic performance of carbonaceous materials in the esterification of succinic acid [J].
Clark, James H. ;
Budarin, Vitaly ;
Dugmore, Thomas ;
Luque, Rafael ;
Macquarrie, Duncan J. ;
Strelko, Volodimir .
CATALYSIS COMMUNICATIONS, 2008, 9 (08) :1709-1714
[5]   Solid acids for green chemistry [J].
Clark, JH .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (09) :791-797
[6]   Selective synthesis of Bisphenol-A over mesoporous MCM silica catalysts functionalized with sulfonic acid groups [J].
Das, D ;
Lee, JF ;
Cheng, SF .
JOURNAL OF CATALYSIS, 2004, 223 (01) :152-160
[7]   Sulfonic acid functionalized mesoporous MCM-41 silica as a convenient catalyst for Bisphenol-A synthesis [J].
Das, D ;
Lee, JF ;
Cheng, SF .
CHEMICAL COMMUNICATIONS, 2001, (21) :2178-2179
[8]   Design of heterogeneous catalysts via multiple active site positioning in organic-inorganic hybrid materials [J].
Dufaud, V ;
Davis, ME .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (31) :9403-9413
[9]   A carbon material as a strong protonic acid [J].
Hara, M ;
Yoshida, T ;
Takagaki, A ;
Takata, T ;
Kondo, JN ;
Hayashi, S ;
Domen, K .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (22) :2955-2958
[10]   Effects of water on biodiesel fuel production by supercritical methanol treatment [J].
Kusdiana, D ;
Saka, S .
BIORESOURCE TECHNOLOGY, 2004, 91 (03) :289-295