Pyridyl-thiazoles as a new class of ligand for metallosupramolecular chemistry:: formation of double and triple helicates with Cu(II)

被引:39
作者
Rice, CR [1 ]
Wörl, S
Jeffery, JC
Paul, RL
Ward, MD
机构
[1] Univ Huddersfield, Dept Chem & Biol Sci, Huddersfield HD1 3DH, W Yorkshire, England
[2] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
关键词
D O I
10.1039/b004319m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of either 1,10-phenanthroline-2-thioamide or pyridine-2-thioamide with 1,4-dibromobutane-2,3-dione affords the novel thiazole-containing polydentate ligands L-1 and L-2, respectively; these ligands form dinuclear double and triple helicate architectures, respectively, with Cu2+.
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页码:1529 / 1530
页数:2
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