Li-ion batteries from LiFePO4 cathode and anatase/graphene composite anode for stationary energy storage

被引:133
作者
Choi, Daiwon [1 ]
Wang, Donghai [1 ]
Viswanathan, Vish V. [1 ]
Bae, In-Tae [2 ]
Wang, Wei [1 ]
Nie, Zimin [1 ]
Zhang, Ji-Guang [1 ]
Graff, Gordon L. [1 ]
Liu, Jun [1 ]
Yang, Zhenguo [1 ]
Duong, Tien [3 ]
机构
[1] Pacific NW Natl Lab, Richland, WA 99352 USA
[2] SUNY Binghamton, Small Scale Syst Integrat & Packaging Ctr, Binghamton, NY 13902 USA
[3] US DOE, Washington, DC USA
关键词
Li-ion battery; LiFePO4; Anatase TiO2; Graphene; Stationary electrical storage; GRAPHITE;
D O I
10.1016/j.elecom.2009.12.039
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Li-ion batteries made from LiFePO4 cathode and anatase TiO2/graphene composite anode were investigated for potential application in stationary energy storage. Fine-structured LiFePO4 was synthesized by a novel molten surfactant approach whereas anatase TiO2/graphene nanocomposite was prepared via self-assembly method. The full cell that operated at 1.6 V demonstrated negligible fade even after more than 700 cycles at measured 1 C rate. While with relative lower energy density than traditional Li-ion chemistries interested for vehicle applications, the Li-ion batteries based on LiFePO4/TiO2 combination potentially offers long life and low cost, along with safety, all which are critical to the stationary applications. Published by Elsevier B.V.
引用
收藏
页码:378 / 381
页数:4
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