Thermal fluctuations of a metal atom on a C60 surface -: art. no. 011201

被引:18
作者
Dugourd, P
Antoine, R
Rayane, D
Benichou, E
Broyer, M
机构
[1] Spectrometrie Ion & Mol Lab, CNRS, UMR 5579, F-69622 Villeurbanne, France
[2] Univ Lyon 1, F-69622 Villeurbanne, France
来源
PHYSICAL REVIEW A | 2000年 / 62卷 / 01期
关键词
D O I
10.1103/PhysRevA.62.011201
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Fluctuations of a rubidium atom on the surface of a fullerene cage have been observed by measuring the electric susceptibility of isolated RbC60 molecules. The evolution of the susceptibility with the temperature is perfectly reproduced with a very simple statistical model of relaxation. The con elation time for these fluctuations and the activation energy (E-a = 0.02 eV) for the motion of the alkali-metal atom on the C-60 surface have been determined.
引用
收藏
页数:4
相关论文
共 24 条
[1]   Static dipole polarizability of small mixed sodium-lithium clusters [J].
Antoine, R ;
Rayane, D ;
Allouche, AR ;
Frécon, MA ;
Benichou, E ;
Dalby, FW ;
Dugourd, P ;
Broyer, M ;
Guet, C .
JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (12) :5568-5577
[2]   Direct measurement of the electric polarizability of isolated C60 molecules [J].
Antoine, R ;
Dugourd, P ;
Rayane, D ;
Benichou, E ;
Broyer, M ;
Chandezon, F ;
Guet, C .
JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (19) :9771-9772
[3]  
ANTOINE R, UNPUB
[4]   A MODEL FOR THERMAL SPIN RELAXATION IN ROTATING FERROMAGNETIC CLUSTERS [J].
BECKER, JA .
ZEITSCHRIFT FUR PHYSIK D-ATOMS MOLECULES AND CLUSTERS, 1994, 29 (04) :299-307
[5]   MAGNETIC-MOMENTS OF IRON CLUSTERS WITH 25 TO 700 ATOMS AND THEIR DEPENDENCE ON TEMPERATURE [J].
BILLAS, IML ;
BECKER, JA ;
CHATELAIN, A ;
DEHEER, WA .
PHYSICAL REVIEW LETTERS, 1993, 71 (24) :4067-4070
[6]   MAGNETIC-PROPERTIES OF FREE COBALT CLUSTERS [J].
BUCHER, JP ;
DOUGLASS, DC ;
BLOOMFIELD, LA .
PHYSICAL REVIEW LETTERS, 1991, 66 (23) :3052-3055
[7]   ON THE DERIVATION OF THE DEBYE THEORY OF DIELECTRIC-RELAXATION FROM THE LANGEVIN EQUATION IN THE PRESENCE OF THE DRIVING FIELD [J].
COFFEY, WT .
JOURNAL OF CHEMICAL PHYSICS, 1990, 93 (01) :724-729
[8]   Theory of relaxation of magnetic clusters in a Stern-Gerlach setup [J].
Dattagupta, S ;
Mahanti, SD .
PHYSICAL REVIEW B, 1998, 57 (17) :10244-10247
[9]  
Debye P. J. W., 1945, POLAR MOL
[10]   SPIN RELAXATION IN SMALL FREE IRON CLUSTERS [J].
DEHEER, WA ;
MILANI, P ;
CHATELAIN, A .
PHYSICAL REVIEW LETTERS, 1990, 65 (04) :488-491