The influence of pressure and composition on the viscosity of andesitic melts

The effect of pressure and composition on the viscosity of both anhydrous and hydrous andesitic melts was studied in the viscosity range of 10(8) to 10(11.5) Pa (.) s using parallel plate viscometry. The pressure dependence of the viscosity of three synthetic, iron-free liquids (andesite analogs) containing 0.0, 1.06, and 1.96 wt.% H2O, respectively, was measured from 100 to 300 MPa using a high-P-T viscometer. These results, combined with those from Richet et al. (1996), indicate that viscosities of anhydrous andesitic melts are independent of pressure, whereas viscosities of hydrous melts slightly increase with increasing pressure. This trend is consistent with an increased degree of depolymerization in the hydrous melts. Compositional effects on the viscosity were studied by comparing iron-free and iron-bearing compositions with similar degrees of depolymerization. During experiments at atmospheric and at elevated pressures (100 to 300 MPa), the viscosity of iron-bearing anhydrous melts preequilibrated in air continuously increased, and the samples became paramagnetic. Analysis of these samples by transmission electron microscopy showed a homogeneous distribution of crystals (probably magnetite) with sizes in the range of 10 to 50 nm. No significant difference in the volume fractions of crystals was found in samples after annealing for 170 to 830 min at temperatures ranging from 970 to 1122 K. An iron-bearing andesite containing 1.88 wt.% H2O, which was synthesized at intrinsic fO(2) conditions in an internally heated pressure vessel, showed a similar viscosity behavior as the anhydrous melts. The continuous increase in viscosity at a constant temperature is attributed to changes of the melt structure due to exsolution of iron-rich phases. By extrapolating the time evolution of viscosity down to the time at which the run temperature was reached, for both the anhydrous (at 1055 K) and the hydrous (at 860 K) iron-bearing andesite, the viscosity is 0.7 log units lower than predicted by the model of Richet et al. (1996). This may be explained by differences in structural properties of Fe2+ and Fe3+ and their substitutes Mg2+, Ca2+, and Al3+, which were used in the analogue composition. The effect of iron redox state on the viscosity of anhydrous, synthetic andesite melts was studied at ambient pressure using a dilatometer. Reduced iron-bearing samples were produced by annealing melts in graphite crucibles in an Ar/CO atmosphere for different run times. In contrast to the oxidized sample, no variation of viscosity with time and no exsolution of iron oxide phases was observed for the most reduced glasses. This indicates that trivalent iron promotes the exsolution of iron oxide in supercooled melts. With decreasing Fe3+/SigmaFe ratio from 0.58 to 0.34, the viscosity decreases by similar to1.6 log units in the investigated temperature range between 964 and 1098 K. A more reduced glass with Fe3+/SigmaFe = 0.21 showed no additional decrease in viscosity. Our conclusion from these results is that the viscosity of natural melts may be largely overestimated when using data obtained from samples synthesized in air. Copyright (C) 2003 Elsevier Science Ltd.