Zero-CO2 emission and low-crossover 'rechargeable' PEM fuel cells using cyclohexane as an organic hydrogen reservoir

被引：28

作者：

Kariya, N ^{[1
]}

Fukuoka, A ^{[1
]}

Ichikawa, M ^{[1
]}

机构：

[1] Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 0600811, Japan

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 06期

关键词：

D O I：

10.1039/b211685e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High performance (open circuit voltage = 920 mV, maximum power density = 14-15 mW cm(-2)) of the PEM fuel cell was achieved by using cyclohexane as a fuel with zero-CO2 emission and lower-crossover through PEM than with a methanol-based fuel cell.

引用

页码：690 / 691

页数：2

共 16 条

[1] Estimation of the membrane methanol diffusion coefficient from open circuit voltage measurements in a direct methanol fuel cell [J].

Barragán, VM ;

Heinzel, A .

JOURNAL OF POWER SOURCES, 2002, 104 (01) :66-72

[2] Electrochemical coupling of benzene hydrogenation and water electrolysis [J].

Itoh, N ;

Xu, WC ;

Hara, S ;

Sakaki, K .

CATALYSIS TODAY, 2000, 56 (1-3) :307-314

[3]

Jarvi TD, 1998, FRONT ELECT, P75

[4] Efficient evolution of hydrogen from liquid cycloalkanes over Pt-containing catalysts supported on active carbons under "wet-dry multiphase conditions" [J].

Kariya, N ;

Fukuoka, A ;

Ichikawa, M .

APPLIED CATALYSIS A-GENERAL, 2002, 233 (1-2) :91-102

[5]

KARIYA N, 2003, IN PRESS APPL CATA A

[6] Recent advances in the development of direct alcohol fuel cells (DAFC) [J].

Lamy, C ;

Lima, A ;

LeRhun, V ;

Delime, F ;

Coutanceau, C ;

Léger, JM .

JOURNAL OF POWER SOURCES, 2002, 105 (02) :283-296

[7] Electrocatalytic oxidation of aliphatic alcohols:: Application to the direct alcohol fuel cell (DAFC) [J].

Lamy, C ;

Belgsir, EM ;

Léger, JM .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (07) :799-809

[8] Direct electro-oxidation of dimethoxymethane, trimethoxymethane, and trioxane and their application in fuel cells [J].

Narayanan, SR ;

Vamos, E ;

Surampudi, S ;

Frank, H ;

Halpert, G ;

Prakash, GKS ;

Smart, MC ;

Knieler, R ;

Olah, GA ;

Kosek, J ;

Cropley, C .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (12) :4195-4201

[9] New fuels as alternatives to methanol for direct oxidation fuel cells [J].

Peled, E ;

Duvdevani, T ;

Aharon, A ;

Melman, A .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (04) :A38-A41

[10] Performance of 2-propanol in direct-oxidation fuel cells [J].

Qi, ZG ;

Kaufman, A .

JOURNAL OF POWER SOURCES, 2002, 112 (01) :121-129

← 1 2 →