Neutral macrocycles via halide-induced ring opening of binuclear condensed intermediates

被引:54
作者
Dixon, FM
Eisenberg, AH
Farrell, JR
Mirkin, CA
Liable-Sands, LM
Rheingold, AL
机构
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Univ Delaware, Dept Chem & Biochem, Newark, DE 19716 USA
关键词
D O I
10.1021/ic000062q
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A novel halide-assisted approach for opening Rh-I-thioether-based condensed intermediates into binuclear macrocycles is reported. This novel ring-opening reaction provides entry into a class of neutral binuclear macrocycles prepared via the "weak-link" synthetic strategy. [GRAPHICS]
引用
收藏
页码:3432 / +
页数:3
相关论文
共 15 条
  • [1] COORDINATION CHEMISTRY AND CATALYSIS WITH HEMILABILE OXYGEN PHOSPHORUS LIGANDS
    BADER, A
    LINDNER, E
    [J]. COORDINATION CHEMISTRY REVIEWS, 1991, 108 (01) : 27 - 110
  • [2] Thin-film molecular materials based on tetrametallic "squares":: Nanoscale porosity and size-selective guest transport characteristics
    Bélanger, S
    Hupp, JT
    Stern, CL
    Slone, RV
    Watson, DF
    Carrell, TG
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (03) : 557 - 563
  • [3] Dol GC, 1998, EUR J INORG CHEM, P1975
  • [4] SYNTHESIS OF POLYTERTIARY PHOSPHINES AND MIXED PHOSPHORUS-SULFUR AND MIXED PHOSPHORUS-NITROGEN POLYDENTATE LIGANDS VIA FREE-RADICAL CATALYSIS
    DUBOIS, DL
    MYERS, WH
    MEEK, DW
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1975, (11): : 1011 - 1015
  • [5] FORMATION OF ANIONIC CARBONYLRHODIUM COMPLEXES FROM WILKINSONS COMPLEX UNDER CONDITIONS OF HYDROFORMYLATION OF FORMALDEHYDE
    EZHOVA, NN
    KORNEEVA, GA
    KURKIN, VI
    FILATOVA, MP
    SLIVINSKY, EV
    [J]. RUSSIAN CHEMICAL BULLETIN, 1995, 44 (05) : 836 - 839
  • [6] Templated formation of binuclear macrocycles via hemilabile ligands
    Farrell, JR
    Eisenberg, AH
    Mirkin, CA
    Guzei, IA
    Liable-Sands, LM
    Incarvito, CD
    Rheingold, AL
    Stern, CL
    [J]. ORGANOMETALLICS, 1999, 18 (23) : 4856 - 4868
  • [7] Strategy for preparing molecular cylinders with synthetically programmable structural parameters
    Farrell, JR
    Mirkin, CA
    Liable-Sands, LM
    Rheingold, AL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (45) : 11834 - 11835
  • [8] Farrell JR, 1998, ANGEW CHEM INT EDIT, V37, P465, DOI 10.1002/(SICI)1521-3773(19980302)37:4<465::AID-ANIE465>3.0.CO
  • [9] 2-A
  • [10] Metal-directed assembly of triple-layered fluorescent metallocyclophanes
    Holliday, BJ
    Farrell, JR
    Mirkin, CA
    Lam, KC
    Rheingold, AL
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (26) : 6316 - 6317