Effects of surface oxide species on the electropolymerization of o-aminophenol on pretreated glassy carbon electrodes

被引：22

作者：

Yang, Y ^{[1
]}

Lin, ZG ^{[1
]}

机构：

[1] XIAMEN UNIV,DEPT CHEM,XIAMEN 316005,PEOPLES R CHINA

来源：

SYNTHETIC METALS | 1996年 / 78卷 / 02期

基金：

中国国家自然科学基金;

关键词：

surface oxide species; electropolymerization; aminophenol; electrodes;

D O I：

10.1016/0379-6779(96)80110-X

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The effects of surface species (e.g. surface oxide species, etc.) on electropolymerization of o-aminophenol on pretreated glassy carbon electrodes are investigated. It is found that surface oxide species can affect the electropolymerization of conducting polymer and electron-transfer rate on the electrochemically pretreated electrode substrate. It is also shown that electropolymerization rate increases with pretreatment potential. However, it is found that nitro groups formed by a chemical method on the electrode surface have a negative effect on the electropolymerization of o-aminophenol. The possible mechanisms are also proposed and discussed.

引用

页码：111 / 115

页数：5

共 26 条

[1] FORMATION OF A NOVEL ELECTROACTIVE FILM BY ELECTROPOLYMERIZATION OF ORTHO-AMINOPHENOL - STUDY OF ITS CHEMICAL-STRUCTURE AND FORMATION MECHANISM - ELECTROPOLYMERIZATION OF ANALOGOUS COMPOUNDS [J].