Electrochemical properties of graphene nanosheet/carbon black composites as electrodes for supercapacitors

被引:564
作者
Yan, Jun [1 ]
Wei, Tong [1 ]
Shao, Bo [1 ]
Ma, Fuqiu [1 ]
Fan, Zhuangjun [1 ]
Zhang, Milin [1 ]
Zheng, Chao [2 ]
Shang, Yongchen [3 ]
Qian, Weizhong [2 ]
Wei, Fei [2 ]
机构
[1] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Minist Educ, Key Lab Superlight Mat & Surface Technol, Harbin 150001, Peoples R China
[2] Tsinghua Univ, Dept Chem Engn, Beijing Key Lab Green Chem React Engn & Technol, Beijing 100084, Peoples R China
[3] Harbin Normal Univ, Dept Chem, Harbin 150080, Peoples R China
关键词
EXFOLIATED GRAPHITE OXIDE; ACTIVATED CARBONS; CAPACITANCE; DISPERSION; SHEETS;
D O I
10.1016/j.carbon.2010.01.014
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Graphene nanosheet/carbon black composites were prepared by the ultrasonication and in situ reduction methods. Microstructure measurements show that most carbon black particles deposit on the edge surfaces of nanosheets by the ultrasonication method, and on the basal surfaces of nanosheets by in situ reduction method. The electrochemical performances of hybrid materials are superior to pure graphene material, demonstrating that carbon black particles as spacers ensured the high electrochemical utilization of graphene layers as well as the open nano-channels provided by three-dimensional graphene nanosheet/carbon black hybrid material. Therefore, the resulting composite is a promising carbon material for supercapacitors. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1731 / 1737
页数:7
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