Synthesis and characterization of nanostructural hydrogel and template for CdS nanofibers

被引:13
作者
Bao, CY [1 ]
Lu, R [1 ]
Jin, M [1 ]
Xue, PC [1 ]
Tan, CH [1 ]
Zhao, YY [1 ]
Liu, GO [1 ]
机构
[1] Jilin Univ, Coll Chem, Changchun 130023, Peoples R China
关键词
hydrogel; self-assemble; CdS nanofibers and template;
D O I
10.1166/jnn.2004.145
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hydrogels based on beta-D-glucopyranoside-substituent thiosemicarbazide derivatives were synthesized and used as template to fabricate netlike CdS nanofibers. The self-assembling properties of the hydrogels and their effect on the synthesis of CdS nanostructure were studied. Fourier transform infrared spectra, UV-visible absorption spectra and X-ray diffraction revealed that pi-pi stacking, hydrogen bonds and interdigitated interactions between hydrophobic chains had influence on the formation of self-assembled lamellar hydrogel. Transmission electron microscopic and electron diffraction observation showed the formation of hexagonal stacking nanofiber-based CdS semiconductor materials. The transmission electron microscopic pictures of the CdS nanostructure in difference growth stages revealed the growth mechanism of CdS nanofibers templated by hydrogel.
引用
收藏
页码:1045 / 1051
页数:7
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