Mn-Ce/ZSM5 as a new superior catalyst for NO reduction with NH3

被引:169
作者
Carja, Gabriela
Kameshima, Yoshikazu
Okada, Kiyoshi
Madhusoodana, Changalla D.
机构
[1] Tech Univ Iasi, Fac Ind Chem, Dept Chem Phys, Iasi, Romania
[2] Tokyo Inst Technol, Dept Met & Ceram Sci, Meguro Ku, Tokyo 1528550, Japan
[3] BHEL Corp, Ceram Technol Inst, Bangalore 560012, Karnataka, India
关键词
SCR; NO reduction; manganese; cerium; ZSM-5;
D O I
10.1016/j.apcatb.2006.06.003
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mn-Ce/ZSM-5 catalyst prepared in an aqueous phase at 423 K exhibits a broad temperature window (517-823 K) for high NO conversions (75-100%) in the process of selective catalytic reduction (SCR) by NH3 even in the presence of H2O and SO2. Both the zeolite matrix and the over-exchanged amounts of manganese and cerium contribute to obtain a complex structure that owns microporous-mesoporous characteristics and specific surface properties. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:60 / 64
页数:5
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