The qualitative probing of hydrogen bond strength by diffusion-ordered NMR spectroscopy

被引:77
作者
Kapur, GS [1 ]
Cabrita, EJ [1 ]
Berger, S [1 ]
机构
[1] Univ Leipzig, Inst Analyt Chem, D-04103 Leipzig, Germany
关键词
hydrogen bonding; diffusion-ordered spectroscopy; DOSY; NMR; diffusion coefficients;
D O I
10.1016/S0040-4039(00)01188-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The feasibility of using diffusion-ordered NMR spectroscopy (DOSY) as a useful probe to qualitatively understand the relative strength of hydrogen bonds between various components in a mixture and a ligand in non-aqueous solutions has been demonstrated. H-1-detected DOSY and P-31-detected DOSY were used. (C) 2000 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:7181 / 7185
页数:5
相关论文
共 14 条
[1]   A three-dimensional DOSY-HMQC experiment for the high-resolution analysis of complex mixtures [J].
Barjat, H ;
Morris, GA ;
Swanson, AG .
JOURNAL OF MAGNETIC RESONANCE, 1998, 131 (01) :131-138
[2]   Direct observation of hydrogen bonds in proteins by interresidue 3hJNC′ scalar couplings [J].
Cordier, F ;
Grzesiek, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (07) :1601-1602
[3]  
Hansen PE, 1997, MAGN RESON CHEM, V35, P520, DOI 10.1002/(SICI)1097-458X(199708)35:8<520::AID-OMR132>3.0.CO
[4]  
2-R
[5]   An NMR investigation of the effect of hydrogen bonding on the rates of rotation about the C-N bonds in urea and thiourea [J].
Haushalter, KA ;
Lau, J ;
Roberts, JD .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (37) :8891-8896
[6]   Diffusion ordered nuclear magnetic resonance spectroscopy: principles and applications [J].
Johnson, CS .
PROGRESS IN NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY, 1999, 34 (3-4) :203-256
[7]   Analysis of hydrocarbon mixtures by diffusion-ordered NMR spectroscopy [J].
Kapur, GS ;
Findeisen, M ;
Berger, S .
FUEL, 2000, 79 (11) :1347-1351
[8]  
Konrat R, 1999, MONATSH CHEM, V130, P961
[9]   DIFFUSION-ORDERED 2-DIMENSIONAL NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY [J].
MORRIS, KF ;
JOHNSON, CS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (08) :3139-3141
[10]   RESOLUTION OF DISCRETE AND CONTINUOUS MOLECULAR-SIZE DISTRIBUTIONS BY MEANS OF DIFFUSION-ORDERED 2D NMR-SPECTROSCOPY [J].
MORRIS, KF ;
JOHNSON, CS .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (10) :4291-4299