Size effects of platinum particles on the electro-oxidation of methanol in an aqueous solution of HClO4

被引:127
作者
Takasu, Y [1 ]
Iwazaki, T [1 ]
Sugimoto, W [1 ]
Murakami, Y [1 ]
机构
[1] Shinshu Univ, Fac Text Sci & Technol, Dept Fine Mat Engn, Nagano 3868567, Japan
关键词
platinum; methanol; oxidation; electrocatalyst; fuel cell;
D O I
10.1016/S1388-2481(00)00101-6
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The 'size effect' of ultrafine platinum particles supported on a carbon material for the electrocatalytic oxidation of methanol has been examined by a model catalyst method. Chronoamperometry revealed that the specific activity of the reaction per real surface area of the platinum particles decreases with a decrease in the platinum particle size. (C) 2000 Published by Elsevier Science S.A.
引用
收藏
页码:671 / 674
页数:4
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