Mechanistic investigations of the formation of TTF derivatives via the phosphonate way

被引：13

作者：

Cristau, HJ

Darviche, F

Torreilles, E

机构：

[1] ENSCM, CNRS, Chim Organ Lab, F-34296 Montpellier 5, France

[2] Univ Montpellier 2, Lab Heterochim & Mat Organ, CNRS, ESA 5076, F-34000 Montpellier, France

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 15期

关键词：

D O I：

10.1016/S0040-4039(98)00061-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

We studied the influence of acetic acid concentration on the deamination and dephosphonylation of the adduct resulting of the nucleophilic reaction between adequate alpha-metalated phosphonate and imminium salt, to enhance the yield of such reactions in order to access efficiently a lot of unsymmetrical TTF derivatives. A mechanism is proposed for the formation of TTF, including steps, i(1) to i(7) The potential concurrent formation of phosphonate (1) under bar and other by-products is also discussed (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：2103 / 2106

页数：4

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