Low loss high dielectric permittivity of polyvinylidene fluoride and KxTiyNi1-x-yO (x=0.05, y=0.02) composites

被引:40
作者
Bhadra, Debabrata [1 ]
Biswas, A. [1 ]
Sarkar, S. [1 ]
Chaudhuri, B. K. [1 ]
Tseng, K. F. [2 ]
Yang, H. D. [2 ]
机构
[1] Indian Assoc Cultivat Sci, Dept Solid State Phys, Kolkata 700032, W Bengal, India
[2] Natl Sun Yat Sen Univ, Dept Phys, Kaohsiung 804, Taiwan
关键词
CRITICAL-BEHAVIOR; CERAMIC-POWDER; CONSTANT; POLYMER; CONDUCTIVITY;
D O I
10.1063/1.3437633
中图分类号
O59 [应用物理学];
学科分类号
摘要
Homogeneous thick film (similar to 0.10 mm) of high dielectric K0.05Ti0.02Ni0.93O; abbreviated as KTNO/polyvinylidene fluoride (PVDF) composite has been prepared by hot-molding technique. The frequency and temperature dependent dielectric behavior of this composite has been studied by varying the KTNO volume fraction (f(KTNO)). Near the percolation threshold (f(KTNO)=0.40), a large enhancement of effective dielectric permittivity (epsilon(eff)similar to 400 which is 40 times higher than that of pure PVDF) with low loss (similar to 0.20 at 1 kHz) is observed. The experimental epsilon(eff) data have been fitted with different theoretical models and found to follow percolation theory successfully. Such a high epsilon(eff) and low loss flexible dielectric material appears to be suitable for technological applications. (c) 2010 American Institute of Physics. [doi:10.1063/1.3437633]
引用
收藏
页数:7
相关论文
共 31 条
[1]   Ceramic-polymer composites with high dielectric constant [J].
Arbatti, Milind ;
Shan, Xiaobing ;
Cheng, Zhongyang .
ADVANCED MATERIALS, 2007, 19 (10) :1369-+
[2]   High-dielectric-constant ceramic-powder polymer composites [J].
Bai, Y ;
Cheng, ZY ;
Bharti, V ;
Xu, HS ;
Zhang, QM .
APPLIED PHYSICS LETTERS, 2000, 76 (25) :3804-3806
[4]   Electroactive polymer actuators and sensors [J].
Bar-Cohen, Yoseph ;
Zhang, Qiming .
MRS BULLETIN, 2008, 33 (03) :173-181
[5]   CRITICAL BEHAVIOR OF COMPLEX DIELECTRIC-CONSTANT NEAR PERCOLATION THRESHOLD OF A HETEROGENEOUS MATERIAL [J].
BERGMAN, DJ ;
IMRY, Y .
PHYSICAL REVIEW LETTERS, 1977, 39 (19) :1222-1225
[7]   Field-activated electroactive polymers [J].
Cheng, Zhongyang ;
Zhang, Qiming .
MRS BULLETIN, 2008, 33 (03) :183-187
[8]  
Cheung M.C., 1999, FERROELECTRICS, V224, P113, DOI [10.1080/00150199908210557, DOI 10.1080/00150199908210557]
[9]   Measurements of universal and non-universal percolation exponents in macroscopically similar systems [J].
Chiteme, C ;
McLachlan, DS .
PHYSICA B-CONDENSED MATTER, 2000, 279 (1-3) :69-71
[10]   Significantly enhanced low-frequency dielectric permittivity in the BaTiO3/poly(vinylidene fluoride) nanocomposite [J].
Dang, Zhi-Min ;
Xu, Hai-Ping ;
Wang, Hai-Yan .
APPLIED PHYSICS LETTERS, 2007, 90 (01)