Improvement of Odor Elimination and Anti-bacterial Activity of Polyester Fabrics Finished with Composite Emulsions of Nanometer Titanium Dioxide-silver Particles-water-borne Polyurethane

被引:35
作者
Chen, Cheng-Chi [2 ]
Wang, Chyung-Chyung [1 ]
Yeh, Jen-Taut [3 ]
机构
[1] Chinese Culture Univ, Dept Text Engn, Taipei 11114, Taiwan
[2] Nanya Inst Technol, Dept Chem & Mat Engn, Tao Yuan 32091, Taiwan
[3] Natl Taiwan Univ Sci & Technol, Dept Polymer Engn, Taipei 10607, Taiwan
关键词
anti-bacteria; composites; finishing; odor elimination; photo-catalyst; water-borne polyurethane; PHYSICAL-PROPERTIES; TIO2; PHOTODEGRADATION; PHOTOCATALYSIS; DISINFECTION; DEGRADATION; OXIDATION; IONS; AG;
D O I
10.1177/0040517508100626
中图分类号
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号
0805 ; 080502 ; 0821 ;
摘要
In this study, two bacteria and three odorous chemicals were employed to assess the antibacterial activity and the odor elimination abilities of fabric samples finished with nanometer titanium dioxide/nanometer silver/water-borne polyurethane (nano-TiO2/nano-Ag/WBPU) composite emulsions. It was found that the value of odor elimination, ultraviolet light transmission, and anti-bacteria for the mixture of nano-TiO2 and nano-Ag was higher than the summed value for the individual nano-TiO2 and nano-Ag. The odor elimination ability for individual nano-TiO2 was better than that for individual nano-Ag, but the anti-bacterial activity was found to follow the opposite trend. The mechanisms of the free radical formation for nano-TiO2-Ag+ have been discussed, suggested and confirmed with the investigation of the energy gap and conductivity values for the individual and the mixed particles of nano-TiO2 and nano-Ag. The loss of the anti-bacterial activity for the fabrics finished with the mixture of nano-TiO2 and nano-Ag was less than 6% and 13% after 15 times' washing and 3000 times' abrasion, respectively. The practicability of the fabrics finished with nano-TiO2/nanoAg/ WBPU composite emulsions was strongly supported by the excellent properties of odor elimination, anti-bacteria, washing fastness and abrasion resistance.
引用
收藏
页码:291 / 300
页数:10
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