A convenient one-step synthesis of formyltetrathiafulvalene vinylogs:: Building blocks for new NLO materials

被引:39
作者
González, M
Martín, N [1 ]
Segura, JL
Garín, J
Orduna, J
机构
[1] Univ Complutense Madrid, Fac Quim, Dept Quim Organ, E-28040 Madrid, Spain
[2] Univ Zaragoza, CSIC, ICMA, Dept Quim Organ, E-50009 Zaragoza, Spain
关键词
D O I
10.1016/S0040-4039(98)00467-5
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A new method for the synthesis of formyltetrathiafulvalene vinylogs in which tetrathiafulvalene (TTF) or a substituted derivative of TTF is metalated with lithium diisopropylamide and then reacted with a vinylogous amide to yield the corresponding short polyenals in a one-pot process is described. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:3269 / 3272
页数:4
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