Synthesis of phenylacetic acid by carbonylation

被引：17

作者：

Duan, JR ^{[1
]}

Jiang, J ^{[1
]}

Gong, JF ^{[1
]}

Fan, QH ^{[1
]}

Jiang, DZ ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2000年 / 159卷 / 01期

关键词：

benzyl alcohol; phenylacetic acid; carbonylation; rhodium catalyst;

D O I：

10.1016/S1381-1169(00)00175-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The carbonylation of benzyl alcohol to phenylacetic acid and its derivatives in the presence of rhodium catalysts is reported in this work. The influence of different reaction conditions, such as total reaction pressure, hydrogen partial pressure, catalyst, promoter and reactant concentrations, as well as reaction temperature on the catalytic activity and selectivity has been investigated. The activation parameters of the carbonylation have been measured and a possible mechanism of the reaction has been proposed. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：89 / 96

页数：8

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