A new oxidation system using nitrite oxidants

被引：9

作者：

Nakamura, A ^{[1
]}

Matsuzaki, T ^{[1
]}

机构：

[1] Ube Ind Ltd, Ube Lab, Ube, Yamaguchi 755, Japan

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 1998年 / 24卷 / 02期

关键词：

D O I：

10.1163/156856798X00780

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The oxidative reactions using alkyl nitrites (RONO) as oxidant have been developed by Ube Industries, Ltd. The substrates such as CO and/or unsaturated-and/or carbonyl-compounds are oxidized by RONO over the palladium catalyst with no contact of molecular oxygen. Dialkyl carbonates, dialkyl oxalates and other useful chemicals are synthesized efficiently under moderate conditions by this alkyl nitrite technology.

引用

页码：213 / 225

页数：13

共 20 条

[1]

ATAKA K, 1992, SHOKUBAI, V34, P130

[2] GAS-PHASE DECOMPOSITION OF ALKOXY RADICALS [J].