Pyridine-pyrazole compound as inhibitor for steel in 1 M HC1

被引:60
作者
Bouklah, M
Attayibat, A
Hammouti, B [1 ]
Ramdani, A
Radi, S
Benkaddour, M
机构
[1] Fac Sci, Lab Chim Eaux & Corros, Oujda, Morocco
[2] Fac Sci, Chim Organ Phys Lab, Oujda, Morocco
关键词
steel; pyridine-pyrazole; inhibition; corrosion; hydrochloric acid;
D O I
10.1016/j.apsusc.2004.07.001
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The influence of 3,5-dimethyl-1H-pyrazole (P1), pyridine (P2) and 2-(3-methyl-1H-pyrazol-5-yl) pyridine (P3) on the corrosion inhibition of steel in molar hydrochloric acid solution is studied using weight-loss potentiodynamic and EIS measurements. Results obtained shows that P3 is the best inhibitor and its inhibition efficiency increases with the increase of concentration to attain 89% since 10(-3) M. Potentiodynamic polarisation studies clearly reveal that it acts essentially as a cathodic inhibitor. The inhibitor studied reduces the corrosion rates. E (%) values obtained from various methods used are in good agreement. Adsorption of P3 on steel surface has an S-shaped adsorption isotherm. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:341 / 348
页数:8
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