Grafting copolymerization of N,N-dimethyacrylaminoethylmethacrylate (DMAEMA) onto preirradiated polypropylene films

被引:21
作者
Chen, Jie [1 ]
Wu, Zaiqian
Yang, Liming
Zhang, Qunfei
Sun, Jie
Shi, Yajuan
Xia, Likai
Kaetsu, Isao
机构
[1] Shanghai Univ, Dept Chem Engn & Technol, Shanghai 201800, Peoples R China
[2] Kinki Univ, Fac Sci & Technol, Higashihiroshima 5770818, Japan
关键词
radiation grafting; polypropylene; DMAEMA; LCST;
D O I
10.1016/j.radphyschem.2007.02.034
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
Grafting copolymerization of dimethylaminoethylmethacrylate (DMAEMA) onto preirradiated polypropylene (PP) films was studied. PP samples were irradiated by electron beam in air. The effects of co-solvent system of ethanol/water (EtOH/H2O), absorbed dose, monomer concentration, reaction time, and reaction temperature on the degree of grafting were determined. The grafted sample films were investigated by Fourier transform infrared (FTIR) spectroscopy in the attenuated total reflectance mode (ATR). (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1367 / 1370
页数:4
相关论文
共 14 条
[1]
The role of partitioning of reagents in grafting and curing reactions initiated by ionizing radiation and UV [J].
Chaplin, RP ;
Dworjanyn, PA ;
Gamage, NJW ;
Garnett, JL ;
Jankiewicz, SV ;
Khan, MA ;
Sangster, DF .
RADIATION PHYSICS AND CHEMISTRY, 1996, 47 (03) :435-437
[2]
Temperature-sensitive swelling behavior of polymer gel composed of poly (N,N-dimethylaminoethyl methacrylate) and its copolymers [J].
Cho, SH ;
Jhon, MS ;
Yuk, SH .
EUROPEAN POLYMER JOURNAL, 1999, 35 (10) :1841-1845
[3]
Cunningham V. L., 1978, US Patent, Patent No. [4129534A, 4129534]
[4]
Cunningham VL, 1977, US Patent US, Patent No. [4052343A, 4052343]
[5]
DING ZL, 1992, INT ATOM EN AG RES C
[6]
OZONE-INDUCED GRAFT-POLYMERIZATION ONTO POLYMER SURFACE [J].
FUJIMOTO, K ;
TAKEBAYASHI, Y ;
INOUE, H ;
IKADA, Y .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1993, 31 (04) :1035-1043
[7]
GRAFTING OF 2-(DIMETHYLAMINO) ETHYL-METHACRYLATE ONTO GAMMA-IRRADIATED POLYPROPYLENE FABRIC [J].
GAWISH, SM ;
KANTOUCH, A ;
ELNAGGAR, AM ;
MOSLEH, S .
JOURNAL OF APPLIED POLYMER SCIENCE, 1992, 44 (09) :1671-1677
[8]
THE RADIATION-INDUCED GRAFT-COPOLYMERIZATION OF METHACRYLIC-ACID WITH POLYETHYLENE - ION-EXCHANGE PROPERTIES OF THE COPOLYMERIC COMPOSITES [J].
GUTHRIE, JT ;
KOTOV, S .
JOURNAL OF APPLIED POLYMER SCIENCE, 1989, 37 (01) :39-54
[9]
Preparation of pH- and thermo-sensitive hydrogel by two-step grafting of acrylamide and acrylic acid onto preirradiated polyethylene film [J].
Hui, BJ ;
Chen, J ;
Yang, LM ;
Li, J ;
Pei, Y ;
Shi, LL .
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2004, 260 (03) :673-677
[10]
Hurlock JR, 2000, US Patent US, Patent No. 6025426