Vapour pressures and enthalpies of vaporization of a series of the ferrocene derivatives

被引:30
作者
Emel'yanenko, Vladimir N.
Verevkin, Sergey P. [1 ]
Krol, Olesya V.
Varushchenko, Raisa M.
Chelovskaya, Nelly V.
机构
[1] Univ Rostock, Dept Phys Chem, D-18055 Rostock, Germany
[2] Moscow MV Lomonosov State Univ, Dept Chem, Moscow, Russia
基金
俄罗斯基础研究基金会;
关键词
ferrocene derivatives; transpiration method; vapour pressure; enthalpy of vaporization; enthalpy of sublimation;
D O I
10.1016/j.jct.2006.09.001
中图分类号
O414.1 [热力学];
学科分类号
摘要
Vapour pressures of the ferrocene, ferrocene-methanol, benzyl-ferrocene, and benzoyl-ferrocene have been determined by the transpiration method. The molar enthalpies of sublimation Delta H-g(cr)m and of vaporization Delta H-g(l)m have been determined from the temperature dependence of the vapour pressure. The molar enthalpies of fusion of these compounds were measured by d.s.c. The measured data sets of vaporization, sublimation, and fusion enthalpies were checked for internal consistency. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:594 / 601
页数:8
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