Plane wave packet study of direct and time-delayed mechanisms in the F+HD reaction

被引：32

作者：

Althorpe, SC ^{[1
]}

机构：

[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England

来源：

CHEMICAL PHYSICS LETTERS | 2003年 / 370卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(03)00105-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The recently developed plane wave packet method is applied to the F + HD reaction on the Stark-Werner potential surface, yielding converged differential cross-sections (d.c.s.) over the collision energy range E = 0-0.15 eV. A wave packet 'movie' is obtained showing how the HF product scatters into space. Two direct and two time-delayed mechanisms are observed. One of the latter corresponds to a recently observed Feshbach resonance. The movie is related to the energy-dependent d.c.s. by a time-dependent d.c.s., which reveals quantum interference between the direct and time-delayed mechanisms. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：443 / 450

页数：8

共 32 条

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