Polypyrazolylborate copper(I) complexes as catalysts of the homogeneous and heterogeneous styrene epoxidation reaction

被引:44
作者
Díaz-Requejo, MM [1 ]
Belderraín, TR [1 ]
Pérez, PJ [1 ]
机构
[1] Univ Huelva, Dept Quim & Ciencia Mat, E-21819 Huelva, Spain
关键词
D O I
10.1039/b004806m
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The complexes BpCu (1) and Tp*Cu (2) catalyse the transformation of styrene into styrene oxide using Oxone as the oxidising agent; the use of silica gel-supported 1 or 2 as heterogeneous catalysts affords similar results, using water as the sole solvent.
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页码:1853 / 1854
页数:2
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