Growth of nanostructured thin films of poly (p-xytylene) derivatives by vapor deposition

被引:39
作者
Cetinkaya, M. [1 ]
Boduroglu, S. [1 ]
Demirel, M. C. [1 ]
机构
[1] Penn State Univ, Dept Engn Sci & Mech, BioNanoMat Grp, University Pk, PA 16802 USA
关键词
nanostructured thin films; paracyclophane; poly-p-xylyiene;
D O I
10.1016/j.polymer.2007.05.015
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Nanostructured thin films of poly(p-xylylene) derivatives are deposited by oblique angle vapor deposition method under low-vacuum conditions. We showed deposition of columnar nanostructured poly(chloro-p-xylylene) and poly(bromo-p-xylylene) thin films, and co-deposition of nanostructured poly(o-trifluoroacetyl-p-xylylene-co-p-xylylene) thin film. Characterization of both the nanostructured and planar thin films of poly(p-xylylene) are performed with different experimental methods. We developed a generalized strategy towards depositing nanostructured poly(p-xylylene) derivatives and thus promise a new generation of thin films suitable for biomedical and antifouling applications. (c) 2007 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4130 / 4134
页数:5
相关论文
共 22 条
[1]   PREPARATION AND STRUCTURE OF DI-P-XYLYLENE [J].
BROWN, CJ ;
FARTHING, AC .
NATURE, 1949, 164 (4178) :915-916
[2]   The chemistry of paper preservation .1. The aging of paper and conservation techniques [J].
Carter, HA .
JOURNAL OF CHEMICAL EDUCATION, 1996, 73 (05) :417-420
[3]   Fibroblast cell attachment and growth on nanoengineered sculptured thin films [J].
Demirel, M. C. ;
So, E. ;
Ritty, T. M. ;
Naidu, S. H. ;
Lakhtakia, A. .
JOURNAL OF BIOMEDICAL MATERIALS RESEARCH PART B-APPLIED BIOMATERIALS, 2007, 81B (01) :219-223
[4]   Bridging simulations and experiments in microstructure evolution [J].
Demirel, MC ;
Kuprat, AP ;
George, DC ;
Rollett, AD .
PHYSICAL REVIEW LETTERS, 2003, 90 (01) :4-016106
[5]   Spatially organized free-standing poly(p-xylylene) nanowires fabricated by vapor deposition [J].
Demirel, Melik C. ;
Boduroglu, Serhan ;
Cetinkaya, Murat ;
Lakhtakia, Akhlesh .
LANGMUIR, 2007, 23 (11) :5861-5863
[6]   COVALENT BINDING OF PD CATALYSTS TO LIGATING SELF-ASSEMBLED MONOLAYER FILMS FOR SELECTIVE ELECTROLESS METAL-DEPOSITION [J].
DRESSICK, WJ ;
DULCEY, CS ;
GEORGER, JH ;
CALABRESE, GS ;
CALVERT, JM .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (01) :210-220
[7]  
Gleiter R., 2004, MODERN CYCLOPHANE CH
[8]   A NEW GENERAL SYNTHETIC METHOD FOR PREPARATION OF LINEAR POLY-P-XYLYLENES [J].
GORHAM, WF .
JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1966, 4 (12PA) :3027-&
[9]  
Hoffmann F, 2006, J NANOSCI NANOTECHNO, V6, P265, DOI 10.1166/jnn.2006.001
[10]  
Lahann J, 1998, MACROMOL RAPID COMM, V19, P441, DOI 10.1002/(SICI)1521-3927(19980901)19:9<441::AID-MARC441>3.0.CO