Straightforward Self-Assembly of Porphyrin Nanowires in Water: Harnessing Adamantane/β-Cyclodextrin Interactions

被引：78

作者：

Fathalla, Maher ^{[1
]}

Neuberger, Amelia ^{[1
]}

Li, Shao-Chun ^{[2
]}

Schmehl, Russell ^{[1
]}

Diebold, Ulrike ^{[2
]}

Jayawickramarajah, Janarthanan ^{[1
]}

机构：

[1] Tulane Univ, Dept Chem, New Orleans, LA 70118 USA

[2] Tulane Univ, Dept Phys & Engn Phys, New Orleans, LA 70118 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 29期

关键词：

HOST-GUEST INTERACTIONS; NANOTUBES; NANORODS; COMPLEXES; SYSTEMS; ARRAYS; LIGAND;

D O I：

10.1021/ja1030722

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convenient approach for the self-assembly of well-defined porphyrin nanowires in water, wherein the individual monomers do not aggregate via pi-pi interactions, is disclosed. These unidirectional and heteromeric assemblies are instead composed of robust beta-CD/adamantane host/guest interactions. A combination of surface microscopies and fluorescence energy transfer experiments were conducted on the nanowires demonstrating their stability and resistance to disassembly.

引用

收藏

页码：9966 / 9967

页数：2

相关论文

共 27 条

[1] Construction of monomeric and polymeric porphyrin compartments by a Pd(II)-pyridine interaction and their chiral twisting by a BINAP ligand [J].

Ayabe, M ;

Yamashita, K ;

Sada, K ;

Shinkai, S ;

Ikeda, A ;

Sakamoto, S ;

Yamaguchi, K .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (03) :1059-1066

[2] Tailoring porphyrins and chlorins for self-assembly in biomimetic artificial antenna systems [J].

Balaban, TS .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (08) :612-623

[3] Counterion dependent dye aggregates:: Nanorods and nanorings of tetra(p-carboxyphenyl)porphyrin [J].

Doan, SC ;

Shanmugham, S ;

Aston, DE ;

McHale, JL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (16) :5885-5892

[4] Self-Organized Porphyrinic Materials [J].

Drain, Charles Michael ;

Varotto, Alessandro ;

Radivojevic, Ivana .

CHEMICAL REVIEWS, 2009, 109 (05) :1630-1658

[5] Nanometer arrays of functional light harvesting antenna complexes by nanoimprint lithography and host-guest interactions [J].

Escalante, Maryana ;

Zhao, Yiping ;

Ludden, Marlon J. W. ;

Vermeij, Rolf ;

Olsen, John D. ;

Berenschot, Erwin ;

Hunter, C. Neil ;

Huskens, Jurriaan ;

Subramaniam, Vinod ;

Otto, Cees .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (28) :8892-+

[6]

FATHALLA M, 2009, J CHEM SOC CHEM COMM, P4209

[7] Multiporphyrin arrays assembled through hydrogen bonding [J].

Gunter, Maxwell J. .

NON-COVALENT MULTI-PORPHYRIN ASSEMBLIES SYNTHESIS AND PROPERTIES, 2006, 121 :263-295

[8] Polymeric Rotaxanes [J].

Harada, Akira ;

Hashidzume, Akihito ;

Yamaguchi, Hiroyasu ;

Takashima, Yoshinori .

CHEMICAL REVIEWS, 2009, 109 (11) :5974-6023

[9] Solutes probe hydration in specific association of cyclodextrin and adamantane [J].

Harries, D ;

Rau, DC ;

Parsegian, VA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (07) :2184-2190

[10]

Huskens J, 2002, ANGEW CHEM INT EDIT, V41, P4467, DOI 10.1002/1521-3773(20021202)41:23<4467::AID-ANIE4467>3.0.CO