Interlocked and interdigitated architectures from self-assembly of long flexible ligands and cadmium salts

被引：493

作者：

Wang, XL

Chao, Q

Wang, EB ^{[1
]}

Lin, X

Su, ZM

Hu, CW

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxomet Chem, Changchun 130024, Peoples R China

[2] NE Normal Univ, Dept Chem, Inst Funct Mat, Changchun 130024, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 38期

关键词：

cadmium; hydrothermal synthesis; luminescence; polymers; supramolecular chemistry;

D O I：

10.1002/anie.200460758

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Noninterpenetrating structures are formed by self-assembly of cadmium salts and long flexible ligands. In one case exceptional ninefold interlocked homochiral helices are built from achiral components (see picture). The helices are chemically independent but physically interwoven. This represents the highest degree of entanglement presently known for a noninterpenetrating system.

引用

页码：5036 / 5040

页数：5

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