The coordination chemistry of 4'-(4-tert-butylphenyl)-2,2':6',2''-terpyridine - A solubilising oligopyridine

被引：26

作者：

Constable, EC

Harverson, P

Smith, DR

Whall, L

机构：

[1] Inst. für Anorganische Chemie, CH-4056 Basel

来源：

POLYHEDRON | 1997年 / 16卷 / 20期

关键词：

D O I：

10.1016/S0277-5387(97)00103-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The preparation of a solubilised 2,2': 6',2''-terpyridine ligand is described together with the characterisation of an unexpected intermediate. Homoleptic complexes of the solubilised ligand 4'-(4-tert-butylphenyl)-2,2': 6',2''-terpyridine, 1, with cobalt(II), cobalt(III), ruthenium(II), iron(II) and nickel(II) have been prepared. The ligand is slightly electron releasing and solubilises the complexes in organic media. (C) 1997 Elsevier Science Ltd.

引用

页码：3615 / 3623

页数：9

共 15 条

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