Chiral metallacyclophane for asymmetric catalysis

被引：78

作者：

Jiang, H ^{[1
]}

Hu, AG ^{[1
]}

Lin, WB ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 01期

关键词：

D O I：

10.1039/b208324h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chiral metallacyclophanes were self-assembled from cis(PEt3)(2)PtCl2 and enantiopure atropisomeric 1,1'-bina-phthyl-6,6-bis(acetylenes) and used in highly enantioselective catalytic diethylzinc additions to aldehydes to afford chiral secondary alcohols.

引用

页码：96 / 97

页数：2

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