Ultrahigh-Energy-Density Microbatteries Enabled by New Electrode Architecture and Micropackaging Design

被引:154
作者
Lai, Wei [1 ]
Erdonmez, Can K. [1 ]
Marinis, Thomas F. [2 ]
Bjune, Caroline K. [2 ]
Dudney, Nancy J. [3 ]
Xu, Fan [3 ]
Wartena, Ryan [1 ]
Chiang, Yet-Ming [1 ]
机构
[1] MIT, Dept Mat Sci & Engn, Cambridge, MA 02139 USA
[2] Charles Stark Draper Lab Inc, Cambridge, MA 02139 USA
[3] Oak Ridge Natl Lab, Mat Sci & Technol Div, Oak Ridge, TN 37831 USA
关键词
ALUMINUM TITANATE CERAMICS; LITHIUM-ION BATTERIES; RECHARGEABLE BATTERIES; THERMAL-EXPANSION; CAPACITY; CATHODES; LICOO2; TRANSITION; DIFFUSION; LIXCOO2;
D O I
10.1002/adma.200903650
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Monolithic cathodes of optimized porosity prepared by sintering LiCoO2 powders provide high volume utilization and surprising stability under electrochemical cycling. Combined with a novel packaging approach, ultrahigh energy densities in small volumes are enabled. The microbatteries have volumes <6 mm(3) and provide sustained similar to 2.5 h discharges with energy densities of 400-650 W h L-1.
引用
收藏
页码:E139 / +
页数:7
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