Chiral metal-organic assemblies - A new approach to immogbilizing homogeneous asymmetric catalysts

被引：134

作者：

Dai, LX ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 43期

关键词：

asymmetric catalysis; bridging ligands; heterogeneous catalysis; immobilization; self-assembly;

D O I：

10.1002/anie.200460301

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Beyond classical immobilized catalysts, metal-ligand polymers self-assembled through coordination are easily prepared, have a robust chiral structure, and display a high density of catalytically active units. These heterogeneous catalysts give excellent results for enantioselective reactions and can be recovered and recycled without significant loss of selectivity.

引用

页码：5726 / 5729

页数：4

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[34]

2-H