Synthesis and structures of carbonyl adducts of the boranes B(BX2)3 (X = F, Cl)

被引:30
作者
Jeffery, JC [1 ]
Norman, NC [1 ]
Pardoe, JAJ [1 ]
Timms, PL [1 ]
机构
[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England
关键词
D O I
10.1039/b007484p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The borane carbonyl adduct (Cl2B)(3)BCO has been prepared and characterised by spectroscopic methods and X-ray crystallography and is compared with the fluorine analogue (F2B)(3)BCO which has also been structurally characterised by X-ray crystallography.
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页码:2367 / 2368
页数:2
相关论文
共 18 条
[1]   TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].
ALLEN, FH ;
KENNARD, O ;
WATSON, DG ;
BRAMMER, L ;
ORPEN, AG ;
TAYLOR, R .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19
[2]   Hydrides of boron VII Evidence of the transitory existence of borine (BH3) borine carbonyl and borme trimethylammine [J].
Burg, AB ;
Schlesinger, HI .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1937, 59 :780-787
[3]  
BURG AB, 1959, J AM CHEM SOC, V81, P3470
[4]  
*CHEM SOC, 1958, SPEC PUBL CHEM SOC, V11, pM18
[5]   CRYSTAL AND MOLECULAR STRUCTURE OF PHOSPHORUS TRIFLUORIDE-TRIS(DIFLUOROBORYL)BORANE B4F6.PF3 [J].
DEBOER, BG ;
ZALKIN, A ;
TEMPLETO.DH .
INORGANIC CHEMISTRY, 1969, 8 (04) :836-&
[6]   Lewis acid properties of tris(pentafluorophenyl)borane.: Structure and bonding in L-B(C6F5)3 complexes [J].
Jacobsen, H ;
Berke, H ;
Döring, S ;
Kehr, G ;
Erker, G ;
Fröhlich, R ;
Meyer, O .
ORGANOMETALLICS, 1999, 18 (09) :1724-1735
[7]   PERHALOGENATED POLYBORON AND SILICON-BORON ANALOGS OF BORANE [J].
KIRK, RW ;
TIMMS, PL ;
SMITH, DL ;
AIREY, W .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1972, (13) :1392-&
[8]  
Lupinetti AJ, 1998, ANGEW CHEM INT EDIT, V37, P2113, DOI 10.1002/(SICI)1521-3773(19980817)37:15<2113::AID-ANIE2113>3.0.CO
[9]  
2-2
[10]  
LUPINETTI AJ, 2000, IN PRESS PROG INORG