[An(H2O)9](CF3SO3)3 (An = U-Cm, Cf): Exploring Their Stability, Structural Chemistry, and Magnetic Behavior by Experiment and Theory

被引：76

作者：

Apostolidis, Christos ^{[2
]}

Schimmelpfennig, Bernd ^{[1
]}

Magnani, Nicola ^{[2
]}

Lindqvist-Reis, Patric ^{[1
]}

Walter, Olaf ^{[3
]}

Sykora, Richard ^{[4
]}

Morgenstern, Alfred ^{[2
]}

Colineau, Eric ^{[2
]}

Caciuffo, Roberto ^{[2
]}

Klenze, Reinhardt ^{[1
]}

Haire, Richard G. ^{[5
]}

Rebizant, Jean ^{[2
]}

Bruchertseifer, Frank ^{[2
]}

Fanghaenel, Thomas ^{[2
]}

机构：

[1] Karlsruhe Inst Technol, Inst Nukl Entsorgung, D-76021 Karlsruhe, Germany

[2] European Commiss, Joint Res Ctr, Inst Transuranium Elements, Karlsruhe, Germany

[3] Karlsruhe Inst Technol, Inst Tech Chem, D-76021 Karlsruhe, Germany

[4] Univ S Alabama, Dept Chem, Mobile, AL 36688 USA

[5] Oak Ridge Natl Lab, Transuranium Res Lab, Div Chem Sci, Oak Ridge, TN USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 36期

关键词：

actinides; coordination modes; hydrates; lanthanides; BASIS-SETS; CRYSTAL-STRUCTURES; TRIVALENT LANTHANIDE; ACTINIDE CHEMISTRY; URANIUM TRIIODIDE; OPTICAL-SPECTRA; IONS; COORDINATION; ENERGY; HYDRATION;

D O I：

10.1002/anie.201001077

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Lanthanide-like: X-ray diffraction and density functional theory studies show that [An(H2O)9]3+ ions of the actinides U3+-Cf3+ in crystals of their triflate salts have the same structure and electrostatic bonding as their lanthanide counterparts La3+-Eu3+. Moreover, the nine-coordinate geometry is essentially preserved in solution for the lighter elements (see picture). Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6343 / 6347

页数：5

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