Semiconducting properties of self-organized TiO2 nanotubes

被引:142
作者
Munoz, A. G. [1 ]
机构
[1] Univ Dusseldorf, Inst Angew Phys, D-40225 Dusseldorf, Germany
关键词
TiO2-nanotubes; impedance spectroscopy; A-semiconductors; Mott-Schottky;
D O I
10.1016/j.electacta.2006.11.035
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The semiconducting properties of anodic grown TiO2-nanotubes were analyzed by means of the potential dependence of the interfacial capacity under different electrolyte and illumination conditions. The experimental results offer evidence for a duplex oxide film conformed by the bottom and wall of pores with different density of donors and concentration of surface states. The surface extension offered by the walls of oxide tubes is manifested in surface related effects such as the shift of the flat band potential and trapping of photoelectrons. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:4167 / 4176
页数:10
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共 42 条
[1]   Sensing mechanism of a carbon monoxide sensor based on anatase titania [J].
Akbar, SA ;
Younkman, LB .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (05) :1750-1753
[2]   CARBON-MONOXIDE AND HYDROGEN DETECTION BY ANATASE MODIFICATION OF TITANIUM-DIOXIDE [J].
BIRKEFELD, LD ;
AZAD, AM ;
AKBAR, SA .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1992, 75 (11) :2964-2968
[3]   Electron trapping in porphyrin-sensitized porous nanocrystalline TiO2 electrodes [J].
Boschloo, GK ;
Goossens, A .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (50) :19489-19494
[4]   Photoelectrochemical study of thin anatase TiO2 films prepared by metallorganic chemical vapor deposition [J].
Boschloo, GK ;
Goossens, A ;
Schoonman, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (04) :1311-1317
[5]   CALCULATION OF THE DYNAMIC-RESPONSE OF SCHOTTKY BARRIERS WITH A CONTINUOUS DISTRIBUTION OF GAP STATES [J].
COHEN, JD ;
LANG, DV .
PHYSICAL REVIEW B, 1982, 25 (08) :5321-5350
[6]   MODELING OF THE IMPEDANCE BEHAVIOR OF AN AMORPHOUS-SEMICONDUCTOR SCHOTTKY-BARRIER IN HIGH DEPLETION CONDITIONS - APPLICATION TO THE STUDY OF THE TITANIUM ANODIC OXIDE ELECTROLYTE JUNCTION [J].
DAFONSECA, C ;
FERREIRA, MG ;
BELO, MD .
ELECTROCHIMICA ACTA, 1994, 39 (14) :2197-2205
[7]   THE ELECTRONIC-PROPERTIES OF DISORDERED PASSIVE FILMS [J].
DEAN, MH ;
STIMMING, U .
CORROSION SCIENCE, 1989, 29 (2-3) :199-211
[8]   Physicochemical characterization of passive films on niobium by admittance and electrochemical impedance spectroscopy studies [J].
Di Quarto, F ;
La Mantia, F ;
Santamaria, M .
ELECTROCHIMICA ACTA, 2005, 50 (25-26) :5090-5102
[9]   Comparative impedance spectroscopy study of rutile and anatase TiO2 film electrodes [J].
Dolata, M ;
Kedzierzawski, P ;
Augustynski, J .
ELECTROCHIMICA ACTA, 1996, 41 (7-8) :1287-1293
[10]   BREAKDOWN AND EFFICIENCY OF ANODIC OXIDE-GROWTH ON TITANIUM [J].
DYER, CK ;
LEACH, JSL .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1978, 125 (07) :1032-1038