Metal-organic frameworks for hydrogen storage

被引：147

作者：

Hirscher, Michael ^{[1
]}

Panella, Barbara ^{[2
]}

Schmitz, Barbara ^{[1
]}

机构：

[1] Max Planck Inst Met Res, D-70569 Stuttgart, Germany

[2] ETH, Inst Chem & Bioengn, Dept Chem & Appl Biosci, CH-8093 Zurich, Switzerland

来源：

MICROPOROUS AND MESOPOROUS MATERIALS | 2010年 / 129卷 / 03期

关键词：

Hydrogen storage; Metal-organic frameworks; Porous materials; Physisorption; Coordination polymers; H-2; BINDING; ADSORPTION; SORPTION; ZN; SATURATION; SITES; CU;

D O I：

10.1016/j.micromeso.2009.06.005

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Physisorption of hydrogen in porous materials at cryogenic conditions is a viable mechanism for hydrogen storage in mobile applications. This storage mechanism has the advantage of possessing fast kinetics, low heat of adsorption and being completely reversible. Among all porous materials, metal-organic frameworks (MOFs) are the best candidates for H(2)-adsorption, since they consist of light atoms, are highly porous and their pore dimensions can be tailored by chemical engineering. Additionally. MOB show the highest storage capacity of any other porous material. Different properties of the material, like specific surface area, composition and pore size can influence the storage capacity. Therefore, an understanding about the correlation between adsorption properties and structure of MOFs is necessary to specifically improve these materials for hydrogen storage. Our main achievements in the investigation of H(2) storage in MOFs are discussed and compared to results reported in literature. (C) 2009 Elsevier Inc. All rights reserved.

引用

页码：335 / 339

页数：5

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