The 4fn⇆4fn-15d transitions of the trivalent lanthanides in halogenides and chalcogenides

被引:836
作者
Dorenbos, P [1 ]
机构
[1] Delft Univ Technol, Inst Interfac Reactor, NL-2629 JB Delft, Netherlands
关键词
trivalent lanthanides; 5d-4f transitions; Stokes shift;
D O I
10.1016/S0022-2313(00)00197-6
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Information from the literature on the energy difference between the 4f(n) ground-state multiplet and the low lying 4f(n-1)5d excited states of Ce3+, Pr3+, Nd3+, Sm3+, Eu3+, Gd3+, Tb3+, Dy3+, Er3+, Tm3+ and Yb3+ doped in about 60 different inorganic compounds has been gathered and studied. It will be demonstrated that once the energy of the first spin allowed 4f(n) --> 4f(n-1)5d transition in any of the above-mentioned lanthanides in a specific compound is known, the corresponding transition energy of all other lanthanides if doped in that same compound can be predicted with an accuracy of typically +/- 600 cm(-1). New estimates will be given for the energy of the first spin-allowed and some of the spin-forbidden fd transitions of all the free (gaseous) triply ionized lanthanides. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:91 / 106
页数:16
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