Hydrogen storage properties in nano-structured magnesium- and carbon-related materials

被引:60
作者
Fujii, H
Orimo, S
机构
[1] Hiroshima Univ, Fac Integrated Arts & Sci, Higashihiroshima 7398521, Japan
[2] Tohoku Univ, Inst Mat Res, Sendai, Miyagi 9808577, Japan
关键词
hydrogen-storage materials; nano-composite materials; thin films; graphite; thermal desorption spectroscopy;
D O I
10.1016/S0921-4526(02)01814-8
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We review hydrogen-storage properties of two nano-structured systems; multi-layered Pd/Mg films prepared by the RF sputtering method and mechanically milled graphite under a high hydrogen atmosphere. The former prepared under optimized RF sputtering conditions absorbs hydrogen of similar to5 mass% at 373 K under 0.1 MPa hydrogen pressure, and desorbs all the hydrogen at 360 K in vacuum. The latter prepared by milling for 80 h absorbs hydrogen up to 7.4 mass%. Hydrogen molecules are desorbed by the two processes above at 600 and 950 K, respectively. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:77 / 80
页数:4
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