Coordination polymers based on square planar Co(II) node and linear spacer: solvent-dependent pseudo-polymorphism and an unprecedented interpenetrating structure containing both 2D and 3D topological isomers

被引:97
作者
Shin, DM
Lee, IS
Chung, YK [1 ]
Lah, MS
机构
[1] Seoul Natl Univ, Coll Nat Sci, Ctr Mol Catalysis, Sch Chem, Seoul 151747, South Korea
[2] LG Chem Ltd, Adv Mat Res Inst, Taejon 305380, South Korea
[3] Han Yang Univ, Coll Sci & Technol, Dept Chem & Appl Chem, Ansan 425170, South Korea
关键词
D O I
10.1039/b210320f
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Reaction of Co(NCS)(2) with 1-methyl-1A-(4-pyridyl)2-(4-pyrimidyl)ethylene (mppe) in different solvents yields two kinds of novel coordination polymer structures of [Co(mppe)(2)( NCS)(2)](n): one of them shows an unprecedented interpenetrating structure with both 2D and 3D topological isomers.
引用
收藏
页码:1036 / 1037
页数:2
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