Catalysis by solid acid: Selective Diels-Alder reactions are promoted by mesoporous aluminosilicate with zinc ions and nanometer honeycomb openings

被引:24
作者
Onaka, M [1 ]
Yamasaki, R [1 ]
机构
[1] Univ Tokyo, Coll Arts & Sci, Dept Chem, Meguro Ku, Tokyo 153, Japan
关键词
D O I
10.1246/cl.1998.259
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Zinc ion-exchanged mesoporous aluminosilicate has been designed specifically to accelerate the Diels-Alder reaction between cyclopentadiene and poor dienophiles such as methyl acrylate and methyl methacrylate. Catalysis on this aluminosilicate is more effective than on a K10-based solid acid catalyst.
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收藏
页码:259 / 260
页数:2
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