Rearrangement of the 1,1-diphenylethoxyl radical is not concerted but occurs through a bridged intermediate

被引：15

作者：

Smeu, Manuel

DiLabio, Gino A.

机构：

[1] Natl Res Council Canada, Natl Inst Nanotechnol, Edmonton, AB T6G 2M9, Canada

[2] Univ Alberta, Dept Phys, Edmonton, AB T6G 2E1, Canada

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 72卷 / 12期

关键词：

D O I：

10.1021/jo070126f

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

Recent experimental observations cast some doubt on the conclusions of earlier work that indicated that the rearrangement of 1,1-diphenylethoxyl radical occurs through a bridged intermediate. We show, by using carefully benchmarked DFT calculations, that the title rearrangement is indeed a two-step reaction.

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页码：4520 / 4523

页数：4

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