Calixarenes as platforms for the construction of multimetallic complexes

被引：64

作者：

Petrella, AJ

Raston, CL ^{[1
]}

机构：

[1] Univ Western Australia, Sch Biomed & Chem Sci, Crawley, WA, Australia

[2] Univ New S Wales, Sch Chem Sci, Sydney, NSW, Australia

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 24期

关键词：

calixarenes; heterometallic complexes; transition metal; group; 1; and; 2; metal center dot center dot center dot pi;

D O I：

10.1016/j.jorganchem.2004.07.065

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review article covers the use of calix[n]arenes (n = 4-6) in building up multi-metal species based on group 1 or 2 ions and early transition metal ions, through synergistic metal-O and metal... pi interactions, depending on the conformation of the calixarenes and the nature of the group 1 or 2 ions. Recent advances on metal alkyl/cyclopentadienyl complexes are also discussed, along with future prospects on the use of calixarenes in general in building up multi-metal complexes in a controlled way. (C) 2004 Elsevier B.V. All rights reserved.

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收藏

页码：4125 / 4136

页数：12

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