Bicyclomangostin: a new acid-catalysed cyclization product from mangostin

被引：6

作者：

Mahabusarakam, W ^{[1
]}

Pakawatchai, C

Wiriyachitra, P

Taylor, WC

Skelton, BW

White, AH

机构：

[1] Prince Songkla Univ, Dept Chem, Hat Yai 90112, Thailand

[2] Chiang Mai Univ, Dept Pharm, Chiang Mai 50002, Thailand

[3] Univ Sydney, Dept Organ Chem, Sydney, NSW 2006, Australia

[4] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1998年 / 51卷 / 03期

关键词：

D O I：

10.1071/C97069

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclization of mangostin with p-toluenesulfonic acid gave 1-isomangostin, 3-isomangostin, and a new cyclization product, bicyclomangostin (4). The structure of bicyclomangostin was determined by spectroscopic and X-ray crystallographic studies. The methyl ether derivatives (8) and (9) or (10) were produced on methylation of bicyclomangostin, depending on the method used.

引用

页码：249 / 254

页数：6

共 8 条

[1]

DUTTA PK, 1987, INDIAN J CHEM B, V26, P281

[2]

HALL SR, 1987, XTAL 2 2 USERS MANUA

[3]

Schmid W., 1855, Justus Liebigs Annalen der Chemie, V93, P83, DOI [DOI 10.1002/JLAC.18550930105, 10.1002/jlac.18550930105]

[4]

STOUT GH, 1968, J CHEM SOC CHEM COMM, P211

[5]

WIRIYACHITRA P, 1986, J SCI SOC THAILAND, V12, P233

[6] ACID-CATALYZED CYCLIZATION OF MANGOSTIN [J].

YATES, P ;

BHAT, HB .

CANADIAN JOURNAL OF CHEMISTRY, 1970, 48 (04) :680-&

[7] DIMETHYLMANGOSTIN HYDROCHLORIDE [J].

YATES, P ;

AULT, A .

TETRAHEDRON, 1967, 23 (08) :3307-&

[8] THE STRUCTURE OF MANGOSTIN [J].

YATES, P ;

STOUT, GH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1958, 80 (07) :1691-1700

← 1 →