Samarium diiodide-promoted diiodomethylation of carbonyl compounds with iodoform.: Synthetic applications of diiodoalcohols

被引：24

作者：

Concellón, JM

Bernad, PL

Pérez-Andrés, JA

机构：

[1] Univ Oviedo, Fac Quim, Dept Quim Organ & Inorgan, Oviedo 33071, Spain

[2] Univ Oviedo, Fac Quim, Inst Quim Organometal, Dept Quim Organ & Inorgan, Oviedo 33071, Spain

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 11期

关键词：

D O I：

10.1016/S0040-4039(97)10777-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A rapid and effective diiodomethylation of carbonyl compounds using SmI2 and iodoform is described. Transformations of the obtained diiodoalcohols 2 into alpha-iodoaldehydes 5 and alpha-hydroxyacids 6 is also reported. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1409 / 1412

页数：4

共 22 条

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[2]

Aston J.G., 1955, ORG SYNTH, V3, P538

[3]

CHAMBERS RD, 1979, COMPREHENSIVE ORGANI, V1, P493

[4]

CONCELLON JM, IN PRESS J ORG CHEM